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biosorption 4

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PCDD/Fs emission, risk characterization, and reduction in China’s secondary copper production industry

Haiqian LI, Yonglong LU, Li LI

Frontiers of Environmental Science & Engineering 2013, Volume 7, Issue 4, Pages 589-597 doi: 10.1007/s11783-013-0495-2

Abstract: Secondary copper production is one of the key polychlorinated dibenzo- -dioxins and dibenzofurans (PCDDIn 2004, when the Stockholm Convention entered into force in China, PCDD/Fs emissions from secondaryIn this paper, PCDD/Fs emission dynamics from secondary copper industry were discussed and cumulativeFrom 2004 to 2009, industrial policies played an indirect role in PCDD/Fs reduction, but its effectsFrom 2009 to 2015, the PCDD/Fs emission dynamics in the secondary copper industry were presented through

Keywords： polychlorinated dibenzo-<italic>pitalic>-dioxins and dibenzofurans (PCDD/Fs) secondary copper production

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Experimental study on low temperature thermal treatment of polychlorinated dibenzo-p-dioxins and dibenzofurans(PCDD/Fs) in fly ash

YAN Jianhua, CHEN Tong, LU Shengyong, LI Xiaodong, GU Yueling, CEN Kefa

Frontiers in Energy 2007, Volume 1, Issue 3, Pages 280-284 doi: 10.1007/s11708-007-0039-1

Abstract: The effects of temperature and time on polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs)The PCDD/Fs in the gas phase and solid phase were detected by high-resolution gas chromatography coupledThe experimental results showed that the major congener was octa-chlorinated dibenzo--dioxin (OCDD) inFs in the solid phase could be decomposed.The optimum condition for PCDD/Fs decomposition in fly ash was a heating time of 60 min at 400 vH under

Keywords： congener polychlorinated temperature chromatography high-resolution

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Detailed analysis of PCBs and PCDD/Fs impurities in a dielectric oil sample (ASKAREL Nr 1740) from an

Jun HUANG, Yamei HUI, Toru MATSUMURA, Gang YU, Shubo DENG, Makoto YAMAUCHI, Changmin WU, Norimasa YAMAZAKI

Frontiers of Environmental Science & Engineering 2014, Volume 8, Issue 2, Pages 195-204 doi: 10.1007/s11783-013-0527-y

Abstract: Homolog and congener profiles of polychlorinated biphenyls (PCBs), polychlorinated dibenzo- - dioxins(PCDDs) and polychlorinated dibenzofurans (PCDFs) in commercial PCBs formulations are useful information

Keywords： profiles of polychlorinated biphenyls (PCBs) polychlorinated dibenzo-<italic>pitalic>-dioxins (PCDDs) polychlorinated dibenzofurans (PCDFs) Askarel transformer insulating fluid

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Legacies and health risks of heavy metals, polybrominated diphenyl ethers, and polychlorinated dibenzo-dioxins

Frontiers of Environmental Science & Engineering 2023, Volume 17, Issue 7, doi: 10.1007/s11783-023-1679-z

Abstract:

● Heavy metals and organic toxins may persist in legacy sites for a long time.

Keywords： E-waste Human health risk Organ risk Heavy metal toxicity PBDE PCDD/F

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Hydrothermal treatment of MSWI fly ash for simultaneous dioxins decomposition and heavy metal stabilization

Jinlong XIE, Yuyan HU, Dezhen CHEN, Bin ZHOU,

Frontiers of Environmental Science & Engineering 2010, Volume 4, Issue 1, Pages 108-115 doi: 10.1007/s11783-010-0013-8

Abstract: hydrothermal treatment of municipal solid waste incineration (MSWI) fly ash were conducted to eliminate dioxinsIn order to enhance decomposing polychlorinated dibenzo-dioxins (PCDDs) and polychlorinated dibenzo-furans

Keywords： municipal solid wastes incineration (MSWI) fly ashes polychlorinated dibenzo-dioxins (PCDDs) polychlorinateddibenzo-furans (PCDFs) hydrothermal heavy metal stabilization

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Distribution of PCDD/Fs in a food waste anaerobic digestion process with biogas utilization

Frontiers of Environmental Science & Engineering 2023, Volume 17, Issue 11, doi: 10.1007/s11783-023-1736-7

Abstract:

● The PCDD/F distribution patterns of the FW-AD process were investigated

Keywords： Biological treatment MSW classification Mass balance Solid digestate

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Atmospheric heterogeneous reaction of chlorobenzene on mineral -FeO particulates: a chamber experiment study

Frontiers of Environmental Science & Engineering 2023, Volume 17, Issue 11, doi: 10.1007/s11783-023-1734-9

Abstract:

● Photochemical conversion of chlorobenzene (CB) on α-Fe₂O₃ was evaluated.

Keywords： Photochemical conversion Chlorobenzene α-Fe₂O₃ PCDD/Fs Mineral particulate

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The <italic>rpoSitalic> deficiency suppresses acetate accumulation in glucose-enriched culture of <italic>Escherichia coliitalic> under an aerobic condition

Prayoga SURYADARMA, Yoshihiro OJIMA, Yuto FUKUDA, Naohiro AKAMATSU, Masahito TAYA

Frontiers of Chemical Science and Engineering 2012, Volume 6, Issue 2, Pages 152-157 doi: 10.1007/s11705-012-1287-0

Abstract: The role of on the central carbon metabolism was investigated through analyzing the deficiency of this regulon gene under aerobic and glucose-enriched culture conditions. The experimental results showed that while the wild type cells exhibited an overflow metabolism effect, the -deleting mutation alleviated this effect with the significant suppression of acetate accumulation under a high glucose condition. This gene deletion also induced the twofold upregulation of and one-tenth downregulation of , respectively. The overflow metabolism effect was confirmed to be recovered by re-introducing gene into the mutant. These results demonstrated changed the central carbon metabolism toward acetate overflow through dehydrogenation of pyruvate and reduction of TCA cycle activity.

Keywords： <italic>Escherichia coliitalic> <italic>rpoSitalic> aerobic and glucose-enriched culture overflow

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Capacity estimation and preliminary strategy for reducing the release of dioxins in China

YU Gang, ZHANG Qing, HUANG Jun, CAI Zhenxiao, SUI Qian

Frontiers of Environmental Science & Engineering 2007, Volume 1, Issue 1, Pages 13-17 doi: 10.1007/s11783-007-0002-8

Abstract: The strategy and action plan for reducing the release of dioxins in China are the most important componentsapplying the best available technology/best environmental practice (BAT/BEP) to reduce the release of dioxinsHow about the capacity for reducing the dioxins release from the key sources?The list of key sources covering about half of the total dioxins release was determined considering fourand that corresponding to the scenario that all key sources have been applied BAT/BEP to reduce the dioxins

Keywords： GIS difference capacity scenario implementation

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Synthesis of depsipeptides from

Hongfei CAO, Yakai FENG, Heyun WANG, Li ZHANG, Musammir KHAN, Jintang GUO

Frontiers of Chemical Science and Engineering 2011, Volume 5, Issue 4, Pages 409-415 doi: 10.1007/s11705-011-1141-9

Abstract: By using the corresponding -amino acid sodium as initiator, -caprolactone-depsipeptides CL-Ala and CL-Leu were prepared by the reactions of -caprolactone (CL) with -alanine and -leucine, respectively, and -dioxanone-depsipeptide (PDO-Leu) was prepared by the reaction of -dioxanone (PDO) with -leucine. Two poly( -caprolactone) oligomers (PCL-Ala and PCL-Leu) of different molecular weights with depsipeptide unit were synthesized by controlling the feed ratio of -amino acid sodium and CL. The presence of the depsipeptide structure in these obtained products was confirmed by H NMR spectra and the molecular weight of the poly( -caprolactone) oligomers was measured by gel permeation chromatography (GPC). These products contain a hydroxyl group and a carboxyl group in one molecule, which means they could act as bifunctional monomers for further polymerization to prepare high molecular weight polymers. By this way, the depsipeptide unit could be introduced into the polymers and the biodegradation rates of the novel polymers could be well controlled in vivo by the tailored molecular structures.

Keywords： <italic>?italic>-caprolactone <italic>pitalic>-dioxanone <italic>Litalic>-alanine <italic>Litalic>-leucine

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Remediation of soil heavily polluted with polychlorinated biphenyls using a low-temperature plasma technique

Xiuhua LI, Haibo ZHANG, Yongming LUO, Ying TENG

Frontiers of Environmental Science & Engineering 2014, Volume 8, Issue 2, Pages 277-283 doi: 10.1007/s11783-013-0562-8

Abstract: Polychlorinated biphenyls PCBs) were removed by low-temperature plasma technique (dielectric barrier

Keywords： polychlorinated biphenyls low-temperature plasma soil contamination intermediate products

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Assessment of toxicity of two nitroaromatic compounds in the freshwater fish

Hongyan SHEN, Jixi GAO, Jinsheng WANG

Frontiers of Environmental Science & Engineering 2012, Volume 6, Issue 4, Pages 518-523 doi: 10.1007/s11783-012-0427-6

Abstract: This study was conducted to evaluate the toxicological response of -nitrotoluene and -nitroaniline to the key fish species, . A freshwater fish bioassay based on the 96 h was used to estimate the single and joint toxicity of the two chemicals. The toxicity of -nitrotoluene was greater than that of -nitroaniline based on 96 h values of 40.74 mg·L and 48.99 mg·L , respectively. Both compounds had moderate toxicity toward , and this toxicity increased with the exposure duration and concentration. Binary mixtures of the compounds were more toxic than the individual compounds at 96 h, and they acted upon partial addition. When the exposure time was longer, the toxicity increased for mixtures of compounds with the same concentration or toxicity. The results of this study suggest that exposure to a combination of these chemicals would result in a higher environmental risk in aquatic systems than exposure to either compound alone. Further research is needed to investigate the combined effects and sublethal toxicity of -nitrotoluene and -nitroaniline, since they are both still used in China.

Keywords： joint toxicity <italic>Cyprinus carpioitalic> <italic>LCitalic>₅₀ <italic>pitalic>-nitrotoluene <italic>pitalic>-nitroaniline toxic unit

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Investigations on color variations of <italic>Morpho rhetenoritalic> butterfly wing scales

Guanglan LIAO, Haibo ZUO, Xuan JIANG, Xuefeng YANG, Tielin SHI

Frontiers of Mechanical Engineering 2012, Volume 7, Issue 4, Pages 394-400 doi: 10.1007/s11465-012-0347-y

Abstract:

Experiments and simulations are carried out to investigate the optical properties of butterfly wing scales. The upper surface of a male butterfly wing presents a single-layer of scales, the microstructures of which are responsible for the brilliant blue color. The color varies from cyan blue to yellow green and soon afterwards returns back to cyan blue when some ethanol is dropped on the upper surface. At the start of the ethanol volatilization process, the reflection spectrum remains stable. As the ethanol further volatilizes, the peak reflectance decreases slightly, then increases dramatically. Meanwhile, the peak wavelength keeps approximately constant, then decreases, and keeps almost stable at the end of the process. Therefore, the optical properties depend strongly on the varying ambient conditions, including the refractive index and the thickness of the packing medium. Moreover, the possible causes for the scales in dark green region after several dropping ethanol experiments are clarified. This research benefits our understanding of the color variation mechanisms of the wing scales, and provides inspiration for further studies and applications.

Keywords： <italic>Morpho rhetenoritalic> microstructures color variations ambient medium

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Administration with

Qi RUI, Qin LU, Dayong WANG

Frontiers of Medicine 2009, Volume 3, Issue 1, Pages 76-90 doi: 10.1007/s11684-009-0002-0

Abstract: During normal metabolism, oxidative byproducts will inevitably generate and damage molecules thereby impairing their biological functions, including the aging process. (补肾抗衰方, ) is a traditional Chinese medicine widely used for clinically treating premature ovarian failure. In the present study, administration at high concentrations significantly increased lifespan, slowed aging-related decline, and delayed accumulation of aging-related cellular damage in wild-type . administration could further largely alleviate the aging defects induced by UV and oxidative stresses, and administration at different concentrations could largely rescue the aging defects in mutant animals. The protective effects of administration on aging process were at least partially dependent on the Ins/IGF-like signaling pathway. Moreover, administration at different concentrations obviously altered the expression patterns of antioxidant genes and suppressed the severe stress responses induced by UV and oxidative stresses, suggesting that -induced tolerance to UV or oxidative stress might result from reactive oxygen species scavenging. administration during development was not necessarily a requirement for UV and oxidative stress resistance, and the concentrations of administrated examined were not toxic for nematodes. Therefore, administration could effectively retrieve the aging defects induced by UV irradiation and oxidative stress in .

Keywords： <italic>Bushenkangshuai Tangitalic> UV irradiation oxidative stress tissue senescence lifespan <italic>Caenorhabditis elegansitalic>

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Mutagenesis and selective breeding of a high producing

Tian WANG, Shiru JIA, Zhilei TAN, Yujie DAI, Shuai SONG, Guoliang WANG

Frontiers of Chemical Science and Engineering 2012, Volume 6, Issue 2, Pages 179-183 doi: 10.1007/s11705-012-1273-6

Abstract: -Poly- -lysine ( -PL) is an -lysine linear homopolymer, which is produced by bacteria belonging to the family and by ergot fungi. However, the production of -PL by the wild bacteria strain is very low, which limits its utilization. In most bacteria including the genus, -lysine is a precursor of -PL and is biosynthesized by the -aspartate pathway. Aspartokinase (Ask) is the first key enzyme in this pathway and is subject to complex regulation such as the feedback inhibition by the end product amino acids. In addition, phosphoenolpyruvate carboxykinase is feedback-regulated by -aspartate. To reduce these feedback inhibitions and to improve -PL productivity, resistant mutants were produced using sulfaguanidine (SG) + glycine+ -lysine+ -3-hydroxynorvaline (AHV) as selective markers. Using the interaction between -PL and the charged dye in the solid culture medium, hundreds of colonies were simultaneously screened in a quick and effective manner. Finally, one -PL-producing strain, L9, was selected. The productivity of this strain during flask fermentation was 0.77 g/L, which was 15% higher than that of the original strain. Moreover, its fermentation performance and genetic characteristics were very stable.

Keywords： <italic>?italic>-poly-<italic>Litalic>-lysine plasma AHV <italic>Streptomyces diastatochromogenesitalic>

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Title Author Date Type Operation

PCDD/Fs emission, risk characterization, and reduction in China’s secondary copper production industry

Haiqian LI, Yonglong LU, Li LI

Journal Article

Experimental study on low temperature thermal treatment of polychlorinated dibenzo-p-dioxins and dibenzofurans(PCDD/Fs) in fly ash

YAN Jianhua, CHEN Tong, LU Shengyong, LI Xiaodong, GU Yueling, CEN Kefa

Journal Article

Detailed analysis of PCBs and PCDD/Fs impurities in a dielectric oil sample (ASKAREL Nr 1740) from an

Jun HUANG, Yamei HUI, Toru MATSUMURA, Gang YU, Shubo DENG, Makoto YAMAUCHI, Changmin WU, Norimasa YAMAZAKI

Journal Article

Legacies and health risks of heavy metals, polybrominated diphenyl ethers, and polychlorinated dibenzo-dioxins

Journal Article

Hydrothermal treatment of MSWI fly ash for simultaneous dioxins decomposition and heavy metal stabilization

Jinlong XIE, Yuyan HU, Dezhen CHEN, Bin ZHOU,

Journal Article

Distribution of PCDD/Fs in a food waste anaerobic digestion process with biogas utilization

Journal Article

Atmospheric heterogeneous reaction of chlorobenzene on mineral -FeO particulates: a chamber experiment study

Journal Article

The <italic>rpoSitalic> deficiency suppresses acetate accumulation in glucose-enriched culture of <italic>Escherichia coliitalic> under an aerobic condition

Prayoga SURYADARMA, Yoshihiro OJIMA, Yuto FUKUDA, Naohiro AKAMATSU, Masahito TAYA

Journal Article

Capacity estimation and preliminary strategy for reducing the release of dioxins in China

YU Gang, ZHANG Qing, HUANG Jun, CAI Zhenxiao, SUI Qian

Journal Article

Synthesis of depsipeptides from

Hongfei CAO, Yakai FENG, Heyun WANG, Li ZHANG, Musammir KHAN, Jintang GUO

Journal Article

Remediation of soil heavily polluted with polychlorinated biphenyls using a low-temperature plasma technique

Xiuhua LI, Haibo ZHANG, Yongming LUO, Ying TENG

Journal Article

Assessment of toxicity of two nitroaromatic compounds in the freshwater fish